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Anti-Nitriding Treatment

Metal mechanical parts such as cams, shafts, pistons, pins, gears or cutting tool parts, in general, are required durability, on the other side, the areas subject to friction also are required a high level of abrasion resistance. Using durable steel materials and only hardening the areas that subject to friction with carburizing and nitriding treatment is a method to achieve both durability and abrasion resistance. In this case, most areas that do not need hardening will be treated with a masking material to ensure durability.
Furthermore, in cases where mechanical processing is required after nitriding, because of masking material coating, it is possible to prevent the formation of a nitriding layer. The masking area has low hardness, so it can improve the durability of the blade for mechanical processing.

Comparison between nitriding area and anti-nitriding area

Material: S45C

Treatment: Gas nitriding treatment at 570oC x 2.5h

 

Surface hardness

HV0.1kg

Compound layer

μm

Cross-sectional photo (x400)
Nitriding area 739 15
Anti-nitriding area 277 0

Comparation between the cross-sectional hardness distribution of the nitriding area and the anti-nitriding area

Distance from surface (mm) 0.05 0.1 0.15 0.2 0.3 0.5 0.7 0.9
Nitriding area 495 480 376 338 277 256 254 243
Anti-nitriding area 239 224 237 244 237 243 236 257

 

Reference (about anti-nitriding)
Nitrogen absorbentation is almost completely prevented.
No changes due to nitrogen diffusion were observed from the microscopic images and cross-sectional hardness distribution.
 
Reference (on the structure of untempered materials)
Looking at the photo, the structure may not be clear, however, at the pale ash color, most of the pearlite is present, and the white areas at the grain boundaries will be ferrite.
We observed the internal organization by changing the vision but did not observe segregation and we concluded that the organization was homogeneous.